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Polymer Chemistry: Differential Scanning Calorimetry

The Differential Scanning Calorimeter 

In a DSC a sample and a reference (often a piece of Indium metal) are contained in small aluminum pans with crimped tops. The pans are placed on individual heaters in a furnace in a nitrogen atmosphere. A diagram of a heat flux DSC furnace is shown at the right58.

The furnace is heated and the temperature difference between the sample and reference is monitored so that the DSC can keep the temperatures the same. If an exothermic phase transition occurs, the temperature of the sample will tend to surge ahead of the reference. In this case the DSC doesn't need to furnish as much heat to the sample. If an endothermic transition occurs, the DSC must furnish more heat to the sample. The electrical power difference between the sample and reference measures the heat flow (dQ/dt) in the sample.

DSC_Cell.gif

The Thermogram 

Data are plotted as heat flow (dQ/dt) against temperature, giving a graph called a thermogram. An example thermogram is shown at the right.

thermogram1.gif

Contributors

  • David Whisnant (Wofford College). Partial support for this work was provided by the National Science Foundation's Division of Undergraduate Education through grants DUE #9950809 and DUE #9950296. Additional support was provided by the Camille and Henry Dreyfus Foundation.