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  • 8.2: Factors Influencing Tg
    https://eng.libretexts.org/Bookshelves/Materials_Science/Polymer_Chemistry_(Whisnant)/08%3A_Transitions/8.02%3A_Factors_Influencing_Tg
    The value of T g depends on the mobility of the polymer chain - the more immobile the chain, the higher the value of T g . In particular, anything that restricts rotational motion within the chain sho...The value of T g depends on the mobility of the polymer chain - the more immobile the chain, the higher the value of T g . In particular, anything that restricts rotational motion within the chain should raise T g . A polymer chain that can move easily will change from a glass to a rubber at a low temperature.
  • 10.4.8.2: Polymer Chemistry- Factors Influencing Tg
    https://eng.libretexts.org/Workbench/Materials_Science_for_Electrical_Engineering/10%3A_Polymer_Properties/10.04%3A_Polymer_Chemistry/10.4.08%3A_Polymer_Chemistry-_Transitions/10.4.8.02%3A_Polymer_Chemistry-_Factors_Influencing_Tg
    The value of T g depends on the mobility of the polymer chain - the more immobile the chain, the higher the value of T g . In particular, anything that restricts rotational motion within the chain sho...The value of T g depends on the mobility of the polymer chain - the more immobile the chain, the higher the value of T g . In particular, anything that restricts rotational motion within the chain should raise T g . A polymer chain that can move easily will change from a glass to a rubber at a low temperature.

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