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  • https://eng.libretexts.org/Bookshelves/Electrical_Engineering/Electronics/Introduction_to_Nanoelectronics_(Baldo)/08%3A_References_and_Appendices/8.05%3A_Appendix_4_-_Hybrid_Orbitals
    Now, if the basis set consists of s and p orbitals, only s and px orbitals can contribute to σ bonds on the x-axis. py and pz orbitals have zero density on the x-axis...Now, if the basis set consists of s and p orbitals, only s and px orbitals can contribute to σ bonds on the x-axis. py and pz orbitals have zero density on the x-axis and therefore cannot contribute to the σ bonds. ϕσ=csϕs+cpxϕpx+cpyϕpy+cpzϕpz

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